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<p class="MsoTitle" style="text-align: center;margin-right: -0.5in; "><b><span style="font-family: 'Times New Roman'; font-size: 13px;">Seminar on</span></b><b><span style="font-family: 'Times New Roman'; font-size: 13px;"> </span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size: 13px;"><b><span style="letter-spacing: 1.5pt; ">Modern Optics and Spectroscopy</span></b></span><b><span style="font-family: Arial; letter-spacing: 1pt; font-size: 13px;"> </span></b></p>
<div><br>
</div>
<p class="MsoNormal" align="center" style="text-align:center"><b><i><span style="letter-spacing: 1pt; font-size: 13px;">New Windows into reaction dynamics</span></i></b><b><i><span style="letter-spacing: 1pt; font-size: 13px;"> </span></i></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b><span style="letter-spacing: 1pt; font-size: 13px;">Arthur Suits,<o:p></o:p></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="letter-spacing: 1pt; font-size: 13px;">Wayne State University<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="letter-spacing: 1pt; font-size: 13px;"> </span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="letter-spacing: 1pt; font-size: 13px;">Tuesday, October 7, 2014</span><span style="font-size: 13px; letter-spacing: 1pt; "> </span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="letter-spacing: 1pt; font-size: 13px;">12:00 – 1:00 p.m.</span></p>
<p class="MsoNormal" style="text-align: center;line-height: 12pt; "><span style="font-size: 13px;">The field of chemical reaction dynamics provides a molecular-level foundation for the understanding of macroscopic chemical phenomena. It is built from the study
of elementary reactions and great strides have been made in the past several decades developing a full quantum description of the simplest chemical reactions. The challenge before us now is to extend these powerful methods to more complex systems: to polyatomic
molecules with many possible product channels in reaction, and to reactions involving multiple excited electronic states. We will showcase three ways in which new spectroscopic and experimental approaches developed in our laboratory yield insight into chemical
reactivity in these frontier areas. The first involves a means to detect simultaneously the velocity and spin polarization of hydrogen atoms in photodissociation. This is turn can yield insight into nonadiabatic transitions at surface crossings in polyatomic
systems. Our second example combines visible and infrared excitation of the nitrate radical to explore the role of roaming dynamics in the ground and excited states of this fascinating molecule. The last example is a new approach combining chirped-pulse microwave
spectroscopy with pulsed uniform supersonic flows, a project being developed in collaboration with the Field group at MIT. This approach promises a new era in the study of reaction dynamics of complex systems with isomer-specific product branching and reaction
kinetics determined using pure rotational spectroscopy.<o:p></o:p></span></p>
<p class="MsoNormal" style="text-align: center;"><span style="font-size: 13px;"> </span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size: 13px;">Grier Room, MIT Bldg 34-401<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size: 13px;">Refreshments served after the lecture</span><font size="6"><o:p></o:p></font></p>
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