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normal"><i style="mso-bidi-font-style:normal"><span style="font-size:24.0pt;
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<o:p></o:p></span></i></b></p>
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normal"><i style="mso-bidi-font-style:normal"><span style="font-size:24.0pt;
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<p class="MsoNormal" align="center" style="text-align:center"><b style="mso-bidi-font-weight:
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<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:24.0pt;mso-bidi-font-size:12.0pt;letter-spacing:1.0pt">Massachusetts Institute of Technology<o:p></o:p></span></p>
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<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:24.0pt;mso-bidi-font-size:12.0pt;letter-spacing:1.0pt">Tuesday, March 19, 2013<o:p></o:p></span></p>
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mso-bidi-font-size:12.0pt;font-family:Times"><o:p><br>
</o:p></span></p>
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<span style="font-size:
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<span style="font-size:13.0pt;font-family:Arial;
mso-bidi-font-family:Arial">Conventional wisdom has always held that transition states are impossible to observe and characterize experimentally. With the exceptions of ultrafast spectroscopy and ab initio
electronic structure calculations, direct information about these critical points on potential energy surfaces has therefore been very limited. We have recently demonstrated for the first time that it is possible to characterize a transition state by high
resolution spectroscopic methods, using the cis-trans isomerization in the well-known A state of acetylene as a prototypical system. New spectroscopic patterns related to the properties of transition states will be discussed, in addition to the experimental
and theoretical techniques employed to decipher the complex spectra and dynamics of isomerizing molecules.<o:p></o:p></span></p>
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<span style="font-size:13.0pt;font-family:Arial;
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<span style="font-size:13.0pt;font-family:Arial;
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<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:18.0pt;mso-bidi-font-size:12.0pt">Grier Room, MIT Bldg 34-401<o:p></o:p></span></p>
<p class="MsoNormal" align="center" style="text-align:center"><span style="font-size:18.0pt;mso-bidi-font-size:12.0pt">Refreshments served after the lecture<o:p></o:p></span></p>
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