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Hello everyone,
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<div class="">This week PLS is excited to virtually host Zoe Todd from the University of Washington. Zoe will be telling us about
<b class="">what the planetary environment can tell us about the origins of life</b>.</div>
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<div class="">Talk details and Zoom information below. (Note: This is the second event of our PLS double-header this week!) We hope to see you there!</div>
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<div class=""><b class="">When: 12:30 PM ET, Tuesday Nov. 9</b></div>
<div class=""><b class="">Zoom</b>: <a href="https://mit.zoom.us/j/92653636868" class="">https://mit.zoom.us/j/92653636868</a></div>
<div class=""><b class="">PW</b>: PLSF2021</div>
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<div class=""><b class="">Title: </b>Ferrocyanide survival under near ultraviolet (300-400 nm) irradiation on the early Earth: implications for prebiotic chemistry</div>
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<div class=""><b class="">Abstract: </b>Prebiotic lake environments containing ferrocyanide could have fostered origins of life chemistry on the early Earth. Ferrocyanide, coupled with sulfite or sulfide, can participate in an ultraviolet (UV)-driven photoredox
cycle to generate solvated electrons, which can reduce cyanide to form all four major building blocks of life: sugars, amino acids, nucleotides, and lipid precursors. However, longer wavelength UV light (~300-400 nm) causes photoaquation of ferrocyanide into
pentacyanoaquaferrate, Fe(CN)5H2O. This species can either regain cyanide to reform ferrocyanide or ultimately lose cyanide ligands, which removes ferrocyanide from solution. Here, we investigate this longwave (300-400 nm) UV-driven loss of ferrocyanide. In
addition to determining the wavelength dependence of the loss and the implications from the UV environment on the early Earth, we also study the effects of pH, temperature, and concentration. We find that in dilute, slightly alkaline solutions, ferrocyanide
would degrade significantly on the order of minutes under the longwave UV radiation expected on the early Earth. We further determine that the lifetime of ferrocyanide is extended at more alkaline pH, lower temperatures, and higher concentrations. Under a
reasonable set of planetary conditions, we find that ferrocyanide lifetimes in irradiated environments range from minutes to hours. Our results can help to determine the constraints implied by the UV-driven loss of ferrocyanide in prebiotic environments. We
assess the potential environmental limits and circumstances that would allow for successful retention of significant amounts of ferrocyanide in prebiotic lakes, with the goal of aiding the construction of consistent and plausible circumstances for prebiotic
chemistry on the early Earth.</div>
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